Stable thiolate adducts of Rh2(OAc)4 – assembly of hexametallic Ni4Rh2 complexes-Reference-Cited by-同舟云学术

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Stable thiolate adducts of Rh2(OAc)4 – assembly of hexametallic Ni4Rh2 complexes

Published:2022 Issue:1 Volume:51 Page:59-62
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Schmorl Sara¹,Börner Martin¹,Kersting Berthold¹^ORCID

Affiliation:

1. Institut für Anorganische Chemie, Universität Leipzig, Johannisallee 29, 04103 Leipzig, Germany

Abstract

Metallothiolate ligands form stable adducts with dirhodium(ii,ii) acetate and allow construction of hexametallic Ni4Rh2 assemblies with magnetic properties.

Funder

Universität Leipzig

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT03509F

Reference44 articles.

1. F. A.Cotton , C. A.Murillo and R. A.Walton , Multiple bonds between metal atoms , Springer Science , New York, NY , 2005

2. Effect of Axial Coordination on the Electronic Structure and Biological Activity of Dirhodium(II,II) Complexes

3. Three Reversible Redox States of Thiolate-Bridged Dirhodium Complexes without Metal–Metal Bonds

4. Catalytic Enantioselective C−H Activation by Means of Metal−Carbenoid-Induced C−H Insertion

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1. Fifty Years of Inorganic Biomimetic Chemistry: From the Complexation of Single Metal Cations to Polynuclear Metal Complexes by Multidentate Thiolate Ligands;European Journal of Inorganic Chemistry;2023-02-22

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