Affiliation:
1. Institut für Anorganische Chemie Universität Leipzig Johannisallee 29 04103 Leipzig Germany
2. Institut de Chimie de Strasbourg UMR 7177 CNRS-Université de Strasbourg 1, rue Blaise Pascal 67008 Strasbourg France
Abstract
AbstractThis article covers 50 years of coordination chemistry of transition metal complexes and metal‐sulfur aggregates involving thiolate‐incorporating ligands by reviewing selected examples. The studies in the coordination chemistry of sulfur‐rich ligands have been undoubtedly triggered and fed by the concomitant development of bioinorganic chemistry, particularly of iron‐sulfur enzymes. The review is broken down in five sections, which examine complexes of increasing nuclearity, including binuclear complexes based on compartmental macrocyclic ligands. We show also how ligand engineering has allowed the researchers in the field to control the nuclearity of the complexes, which was a particularly difficult task for sulfur‐based ligands, as thiolates show a strong tendency to coordinate to more than one metal cation at once.
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