Redox-neutral remote amidation of alkenyl alcohols <i>via</i> long-range isomerization/transformation-Reference-Cited by-同舟云学术

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Redox-neutral remote amidation of alkenyl alcohols via long-range isomerization/transformation

Published:2022 Issue:21 Volume:9 Page:5942-5948
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Bai Na¹,Wang Xuchao¹,Wang Zhenchao²^ORCID,Liu Feipeng¹,Rong Zi-Qiang¹^ORCID

Affiliation:

1. Frontiers Science Center for Flexible Electronics (FSCFE), Shaanxi Institute of Flexible Electronics (SIFE) & Shaanxi Institute of Biomedical Materials and Engineering (SIBME), Northwestern Polytechnical University (NPU), 127 West Youyi Road, Xi'an 710072, China

2. College of Pharmacy, Guizhou University, Guiyang, Guizhou 550025, China

Abstract

A facile and straightforward approach for the construction of amides via redox-neutral Ru-catalyzed cross-coupling reaction of long-range alkenyl alcohols with amines to realize remote site-selective functionalization has been developed.

Funder

Chunhui Project Foundation of the Education Department of China

Young Talent Support Program of Shaanxi Province University

Northwestern Polytechnical University

Natural Science Basic Research Program of Shaanxi Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QO/D2QO01143C

Reference85 articles.

1. Remote functionalization of C-H and C-C bonds by "naked" transition-metal ions (Cosi Fan Tutte)

2. Ruthenium-Catalyzed Isomerization of Terminal Olefins: Applications to Synthesis

3. Mechanistic Studies on Hydrocyanation Reactions

4. Isomerization–Hydroformylation Tandem Reactions

5. Isomerization of Allylbenzenes

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