Reactivity of an NHC-stabilized pyramidal hydrosilylene with electrophilic boron sources-Reference-Cited by-同舟云学术

Reactivity of an NHC-stabilized pyramidal hydrosilylene with electrophilic boron sources

Published:2019 Issue:17 Volume:48 Page:5756-5765
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Dübek Gizem¹²³⁴⁵^ORCID,Franz Daniel¹²³⁴⁵^ORCID,Eisenhut Carsten⁶⁷⁸⁵,Altmann Philipp J.¹²³⁴⁵,Inoue Shigeyoshi¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. WACKER-Institute of Silicon Chemistry and Catalysis Research Centre

3. Technische Universität München

4. 85748 Garching bei München

5. Germany

6. Institut für Chemie

7. Technische Universität Berlin

8. 10623 Berlin

Abstract

An NHC-stabilized three-coordinate hydrosilylene dehydrogenates ammonia borane and forms more stable complexes with BH₃, BPh₃, BBr₃ and BPhBr₂ but less stable ones with BF₃, and BCl₃ for which ligand scrambling occurs.

Funder

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00608G

Reference77 articles.

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