Inverse and highly selective separation of CO2/C2H2 on a thulium–organic framework

Author:

Ma Deyun12345ORCID,Li Zhi67894,Zhu Jiaxing1011124ORCID,Zhou Yiping1234,Chen Lilin1234,Mai Xufeng1234,Liufu Meilin1234,Wu Yinbing1234,Li Yingwei51314154ORCID

Affiliation:

1. School of Food and Pharmaceutical Engineering

2. Zhaoqing University

3. Zhaoqing 526061

4. China

5. State Key Laboratory of Pulp and Paper Engineering

6. Shandong Provincial Key Laboratory of Molecular Engineering

7. QiLu University of Technology

8. Shandong Academy of Sciences

9. Jinan 250353

10. Department of Chemistry

11. Fudan University

12. Shanghai 200433

13. School of Chemistry and Chemical Engineering

14. South China University of Technology

15. Guangzhou 510640

Abstract

A new Tm-based complex 1 is synthesized and activated at different temperatures to obtain two porous MOFs (1a and 1a′) with different pore sizes and pore surfaces, in which 1a shows an excellent capability to selectively capture CO2 from CO2/C2H2.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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