Separation of Hexane Isomers in a Metal-Organic Framework with Triangular Channels-Reference-Cited by-同舟云学术

Separation of Hexane Isomers in a Metal-Organic Framework with Triangular Channels

Published:2013-05-24 Issue:6135 Volume:340 Page:960-964
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Herm Zoey R.¹,Wiers Brian M.¹,Mason Jarad A.¹,van Baten Jasper M.²,Hudson Matthew R.³,Zajdel Pawel⁴,Brown Craig M.³⁵,Masciocchi Norberto⁶,Krishna Rajamani²,Long Jeffrey R.¹

Affiliation:

1. Department of Chemistry, University of California, Berkeley, CA 94720, USA.

2. Van’t Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, Netherlands.

3. Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, MD 20899, USA.

4. Institute of Physics, University of Silesia, ul. Uniwersytecka 4, 40-007 Katowice, Poland.

5. Chemical and Biomolecular Engineering, University of Delaware, Newark, DE 19716, USA.

6. Dipartimento di Scienza e Alta Tecnologia, Università dell’Insubria, via Valleggio 11, I-22100 Como, Italy.

Abstract

Telling Hexanes Apart The efficiency of modern internal combustion engines depends on the relative reactivity of the hydrocarbons that comprise the fuel. In particular, branched hydrocarbons are less likely than their linear counterparts to react prematurely—a property reflected in the fuel mixture's octane number. Herm et al. (p. 960 ) report a metal organic framework material with triangular pore channels that discriminate among the differently shaped isomers of hexane more finely than the commercial standard.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference69 articles.

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5. Hydrogen Storage in Metal–Organic Frameworks

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