Effect of aromatic ring substituents on the ability of catechol to produce brown carbon in iron(iii)-catalyzed reactions
Author:
Affiliation:
1. Department of Chemistry
2. University of California
3. Irvine
4. USA
5. Department of Chemistry and Biochemistry
6. Wilfrid Laurier University
7. Waterloo
8. Canada
Abstract
Our previous work demonstrated formation of highly insoluble and strongly light-absorbing organic particles in reactions between catechol or guaiacol with Fe(iii) under pH = 3 conditions characteristic of aerosol liquid water.
Funder
National Science Foundation
Natural Sciences and Engineering Research Council of Canada
University of California
Publisher
Royal Society of Chemistry (RSC)
Link
http://pubs.rsc.org/en/content/articlepdf/2021/EA/D0EA00007H
Reference57 articles.
1. The formation, properties and impact of secondary organic aerosol: current and emerging issues
2. Formation of Light Absorbing Soluble Secondary Organics and Insoluble Polymeric Particles from the Dark Reaction of Catechol and Guaiacol with Fe(III)
3. Effect of Oxalate and Sulfate on Iron-Catalyzed Secondary Brown Carbon Formation
4. Characterization of Light-Absorbing Oligomers from Reactions of Phenolic Compounds and Fe(III)
5. Formation of brown carbon on Fe-bearing clay from volatile phenol under simulated atmospheric conditions
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