Copper(i)-catalyzed asymmetric exo-selective [3+2] cycloaddition of azomethine ylides with β-trifluoromethyl β,β-disubstituted enones-Reference-Cited by-同舟云学术

Copper(i)-catalyzed asymmetric exo-selective [3+2] cycloaddition of azomethine ylides with β-trifluoromethyl β,β-disubstituted enones

Published:2017 Issue:58 Volume:53 Page:8152-8155
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Xu Bing¹²³⁴⁵,Zhang Zhan-Ming¹²³⁴⁵,Liu Bing¹²³⁴⁵,Xu Shan¹²³⁴⁵,Zhou Lu-Jia¹²³⁴⁵,Zhang Junliang¹²³⁴⁵^ORCID

Affiliation:

1. Shanghai Key Laboratory of Green Chemistry and Chemical Process

2. School of Chemistry and Molecular Engineering

3. East China Normal University

4. Shanghai 200062

5. China

Abstract

A copper-catalyzed asymmetricexo-selective dipolar cycloaddition of β-trifluoromethyl β,β-disubstituted enones with azomethine ylides was developed, which provides an efficient access to valuable pyrrolidines bearing a trifluoromethylated all-carbon quaternary stereocenter.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC03015K

Reference67 articles.

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