β-Trifluoromethylated enones as trifluoromethylated synthons in asymmetric catalysis

Author:

Cheng Xiufang1,Niu Wenjin1,Wang Huamin1ORCID,Lin Ying-Wu12ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, University of South China, Hengyang, P. R. China

2. Laboratory of Protein Structure and Function, University of South China Medical School, Hengyang, P. R. China

Abstract

This minireview describes the applications of β-trifluoromethylated enones in diverse asymmetric catalytic transformations since 2008, and incorporates the mechanistic aspects, involving the key mechanistic intermediates and the reaction pathways.

Funder

Natural Science Foundation ofHunan Province

Scientific Research Foundation of Hunan Provincial Education Department

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Reference98 articles.

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2. A.Collins , G.Sheldrake and J.Crosby , Chirality in Industry II: Developments in the Commercial Manufacture and Applications of Optically Active Compounds , John Wiley & Sons Ltd , Chichester , 1997

3. Engineering chiral porous metal-organic frameworks for enantioselective adsorption and separation

4. The Significance of Chirality in Drug Design and Development

5. K.Ding and Y.Uozumi , Handbook of Asymmetric Heterogeneous Catalysis , Wiley-VCH , New York , 2008

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