Anti-sieve effect in guest inclusion by thiacalix[4]arene giving a surge in thermal stability of its clathrates prepared by solid-phase guest exchange
Author:
Affiliation:
1. Kazan Federal University
2. A.M. Butlerov Institute of Chemistry
3. Kazan, Russia
4. A.E. Arbuzov Institute of Organic and Physical Chemistry
5. 420088 Kazan, Russia
6. Institute of Organic Chemistry of NAS of Ukraine
7. Kiev, Ukraine
Abstract
The unusual exclusion of smaller guests by host may be avoided by solid-phase exchange in preparation of clathrates, which thus become extremely thermally stable.
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/CE/C3CE42304B
Reference17 articles.
1. Acetylene and argon adsorption in a supramolecular organic zeolite
2. Storage of Methane and Freon by Interstitial van der Waals Confinement
3. Unusually High Selectivity of Guest Exchange in tert-Butylthiacalix[4]arene Clathrate Producing More Thermostable Inclusion and Memory of Guest
4. Nonlinear Structure−Affinity Relationships for Vapor Guest Inclusion by Solid Calixarenes
5. Nonregular structure–property relationships for inclusion parameters of tert-butylcalix[5]arene
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4. Selective guest inclusion by crystals of calixarenes: potential for application as separation materials;Journal of Inclusion Phenomena and Macrocyclic Chemistry;2018-02-03
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