B–H and O–H bonds activation via a single electron transfer of frustrated radical pairs
Author:
Affiliation:
1. Zhang Dayu School of Chemistry
2. Dalian University of Technology
3. Dalian 116024
4. P. R. China
5. CAS Key Laboratory of Separation Science for Analytical Chemistry
Abstract
The combination of TEMPO radicals with Lewis acidic boranes enables the cleavage of B–H and O–H bonds via a one-electron process.
Funder
National Natural Science Foundation of China
Fundamental Research Funds for the Central Universities
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT01169C
Reference56 articles.
1. Reversible, Metal-Free Hydrogen Activation
2. Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane–borane adduct
3. Frustrated Lewis Pairs: Discovery and Overviews in Catalysis
4. New Directions for Frustrated Lewis Pair Chemistry
5. Ambiphilic Molecules: From Organometallic Curiosity to Metal-Free Catalysts
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