A mechanistic insight into metal-cluster π-envelopment: a dual binding mode involving bent and planar ligand-conformers-Reference-Cited by-同舟云学术

A mechanistic insight into metal-cluster π-envelopment: a dual binding mode involving bent and planar ligand-conformers

Published:2016 Issue:38 Volume:52 Page:6427-6430
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Masai Kohei¹²³⁴⁵,Shirato Katsunori⁶⁷⁸⁹⁵,Yamamoto Koji¹⁰¹¹¹²⁵,Kurashige Yuki¹³¹¹¹²⁵,Murahashi Tetsuro¹²³⁴⁵

Affiliation:

1. Department of Chemical Science and Engineering

2. School of Materials and Chemical Technology

3. Tokyo Institute of Technology

4. Meguro-ku

5. Japan

6. Department of Applied Chemistry

7. Graduate School of Engineering

8. Osaka University

9. Suita

10. Research Center of Integrative Molecular Systems

11. Institute for Molecular Science

12. Okazaki

13. Department of Theoretical and Computational Molecular Science

Abstract

We report a stepwise mechanism of the π-envelopment of a Pd₄ chain cluster. Bent- and planar binding modes of π-conjugated unsaturated hydrocarbon ligands are involved in the π-envelopment process.

Funder

Ministry of Education, Culture, Sports, Science, and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC01536K

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