Photo-induced translocation of a Pdn moiety (n = 2, 7) on a conjugated polyene ligand-Reference-Cited by-同舟云学术

Photo-induced translocation of a Pdn moiety (n = 2, 7) on a conjugated polyene ligand

Published:2019 Issue:35 Volume:48 Page:13149-13153
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Yamashita Mitsuki¹²³⁴,Horiuchi Shinnosuke⁵⁶⁷⁴^ORCID,Yamamoto Koji¹²³⁴,Murahashi Tetsuro¹²³⁴^ORCID

Affiliation:

1. Department of Chemical Science and Engineering

2. Tokyo Institute of Technology

3. Tokyo

4. Japan

5. Research Center of Integrative Molecular Systems

6. Institute for Molecular Science

7. Aichi 444-8787

Abstract

The Pd₂-translocation on a tetraene ligand is switchable between the thermodynamic equilibrium state and the photo-stationary state. The Pd₇-translocation on a carotene ligand proceeds smoothly under photo-irradiation.

Funder

Japan Society for the Promotion of Science

Asahi Glass Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT03073E

Reference32 articles.

1. Contiguous multiple π-coordination of π-conjugated polyenes: bonding nature and charge delocalization behaviour of polyene–(palladium chain) sandwich clusters

2. Organometallic Sandwich Chains Made of Conjugated Polyenes and Metal−Metal Chains

3. Photoinduced Face-Inversion of Conjugated Tetraene Ligands on a Pd−Pd−Pd Moiety

4. Perylene−Tetrapalladium Sandwich Complexes

5. Stepwise growth of polypalladium chains in 1,4-diphenyl-1,3-butadiene sandwich complexesElectronic supplementary information (ESI) available: structural details. See http://www.rsc.org/suppdata/cc/b4/b403098b/

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