A novel 1,3,5-triaminocyclohexane-based tripodal ligand forms a unique tetra(pyrazolate)-bridged tricopper(ii) core: solution equilibrium, structure and catecholase activity-Reference-Cited by-同舟云学术

A novel 1,3,5-triaminocyclohexane-based tripodal ligand forms a unique tetra(pyrazolate)-bridged tricopper(ii) core: solution equilibrium, structure and catecholase activity

Published:2016 Issue:38 Volume:45 Page:14998-15012
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Szorcsik Attila¹²³,Matyuska Ferenc⁴⁵²³,Bényei Attila⁶⁷⁸³,Nagy Nóra V.⁹¹⁰¹¹³,Szilágyi Róbert K.¹²¹³¹⁴¹⁵¹⁶,Gajda Tamás¹²³⁴⁵

Affiliation:

1. MTA-SZTE Bioinorganic Chemistry Research Group

2. H-6720 Szeged

3. Hungary

4. Department of Inorganic and Analytical Chemistry

5. University of Szeged

6. Department of Physical Chemistry

7. University of Debrecen

8. Debrecen H-4032

9. Institute of Organic Chemistry

10. Research Centre for Natural Sciences HAS

11. H-1117 Budapest

12. Department of Chemistry and Biochemistry

13. Montana State University

14. Bozeman

15. USA

16. Department of Analytical Chemistry

Abstract

A polydentate tripodal ligand forms a series of tricopper(ii) complexes, that feature unique pyrazolate-bridged linear core. The Cu₃H₋₃L₂ complex is an efficient catecholase mimic with a surprisingly low pH optimum at pH = 5.6.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT01228K

Reference78 articles.

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