Triptycene-supported bimetallic salen porous organic polymers for high efficiency CO2 fixation to cyclic carbonates

Author:

Zheng Yingting12345,Wang Xiqian12345,Liu Chao12345,Yu Baoqiu12345,Li Wenliang6789ORCID,Wang Hailong12345ORCID,Sun Tingting12345,Jiang Jianzhuang12345ORCID

Affiliation:

1. Beijing Advanced Innovation Center for Materials Genome Engineering

2. Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials

3. Department of Chemistry and Chemical Engineering

4. School of Chemistry and Biological Engineering

5. University of Science and Technology Beijing

6. Faculty of Chemistry

7. Northeast Normal University

8. Changchun 130024

9. China

Abstract

Triptycene units in bimetallic salen POPs are envisaged to support the alignment of bimetallic salen macrocycles in side walls of channels for exposing more metal active sites resulting in the high efficiency coupling reaction of epoxides with CO2.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

University of Science and Technology Beijing

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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