From a 1,2-azaborinine to large BN-PAHs via electrophilic cyclization: synthesis, characterization and promising optical properties

Author:

Appiarius Yannik12345ORCID,Stauch Tim53416ORCID,Lork Enno16341ORCID,Rusch Pascal73489,Bigall Nadja C.73489ORCID,Staubitz Anne12345ORCID

Affiliation:

1. University of Bremen

2. Institute for Analytical and Organic Chemistry

3. D-28359 Bremen

4. Germany

5. MAPEX Center for Materials and Processes

6. Institute for Physical and Theoretical Chemistry

7. Bremen Center for Computational Materials Science

8. Leibniz University Hannover

9. Institute for Physical Chemistry and Electrochemistry

Abstract

A synthetic approach towards boron-nitrogen substituted polycyclic aromatic hydrocarbons (BN-PAHs) via electrophilic cyclization is described and it is shown that the variation of the rings' connectivity may tune the emission wavelengths effectively.

Funder

Deutsche Forschungsgemeinschaft

Horizon 2020

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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