Boosting quantum yields and circularly polarized luminescence of penta- and hexahelicenes by doping with two BN-groups

Author:

Appiarius Yannik12ORCID,Míguez-Lago Sandra3ORCID,Puylaert Pim4ORCID,Wolf Noah1ORCID,Kumar Sourabh5ORCID,Molkenthin Martin1,Miguel Delia6ORCID,Neudecker Tim257ORCID,Juríček Michal8ORCID,Campaña Araceli G.3ORCID,Staubitz Anne12ORCID

Affiliation:

1. University of Bremen, Institute for Organic and Analytical Chemistry, 28359 Bremen, Germany

2. University of Bremen, MAPEX Center for Materials and Processes, 28359 Bremen, Germany

3. University of Granada, Department of Organic Chemistry, Unidad de Excelencia de Química, 18071 Granada, Spain

4. University of Bremen, Institute for Inorganic Chemistry and Crystallography, 28359 Bremen, Germany

5. University of Bremen, Institute for Physical and Theoretical Chemistry, 28359 Bremen, Germany

6. University of Granada, Department of Physical Chemistry, Unidad de Excelencia de Química, 18071 Granada, Spain

7. University of Bremen, Bremen Center for Computational Materials Science, 28359 Bremen, Germany

8. University of Zurich, Department of Chemistry, 8057 Zurich, Switzerland

Abstract

The presented penta- and hexahelicenes with two boron–nitrogen groups resemble their all-carbon analogs structurally but show considerably improved (chir)optical properties like absorptivities, quantum yields and luminescence dissymmetries.

Funder

Junta de Andalucía

Ministerio de Economía y Competitividad

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

European Regional Development Fund

H2020 European Research Council

Universität Bremen

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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