Magnetocaloric effect and slow magnetic relaxation in two dense (3,12)-connected lanthanide complexes-Reference-Cited by-同舟云学术

Magnetocaloric effect and slow magnetic relaxation in two dense (3,12)-connected lanthanide complexes

Published:2014 Issue:7 Volume:1 Page:549-552
ISSN:2052-1553
Container-title:Inorg. Chem. Front.
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Han Song-De¹²³⁴,Miao Xiao-Hong¹²³⁴,Liu Sui-Jun¹²³⁴,Bu Xian-He¹²³⁴

Affiliation:

1. Department of Chemistry

2. TKL of Metal- and Molecule-Based Material Chemistry and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)

3. Nankai University

4. Tianjin 300071, P.R. China

Abstract

We report two (3,12)-connected complexes with distorted cubic [Ln₄O₄] (Ln = Gd (1), Dy (2)) units as nodes bridged by in situ generated sulfate. 1 features a large magnetocaloric effect with −ΔSmaxm = 51.29 J kg⁻¹ K⁻¹, and 2 displays slow magnetic relaxation behavior.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/QI/C4QI00073K

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