A chiral sodium lanthanum sulfate for second-order nonlinear optics and proton conduction

Author:

Fu Hao12,Zhang Xiaohui1,Liu Peiyu1,Li Bo3,Wu Baolin4,Tao Ye1,Lu Qianshuang1,Li Yingjie1,Huang Jiaxi1,Zhang Fangfang5ORCID,He Tingchao6ORCID,Chen Zhi1ORCID,Wang Heng7,Su Chenliang2ORCID,Zang Hong-Ying3,Yu Xiujun1ORCID,Li Xiaopeng178ORCID

Affiliation:

1. College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, Guangdong 518060, China

2. Institute of Microscale Optoelectronics, Shenzhen University, Shenzhen, Guangdong 518060, China

3. Key Laboratory of Polyoxometalate Science, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China

4. Fundamental electrochemistry (IET-1), Institute of Energy Technologies, Forschungszentrum Jülich GmbH, Wilhelm-Johnen-Straße, Jülich 52425, Germany

5. Research Center for Crystal Materials, Xinjiang Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Urumqi, Xinjiang 830011, China

6. Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen, Guangdong 518060, China

7. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shanghai 200032, China

8. Shenzhen University General Hospital, Shenzhen University Clinical Medical Academy, Shenzhen University, Shenzhen, Guangdong 518055, China

Abstract

We have rationally synthesized a chiral sodium lanthanum sulfate, NaLa(SO4)2(H2O), through the complementary integration of alkali and rare-earth cations. The compound exhibits a high proton conductivity and SHG response with a high birefringence.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

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