Reduction of CO2 by a masked two-coordinate cobalt(i) complex and characterization of a proposed oxodicobalt(ii) intermediate-Reference-Cited by-同舟云学术

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Reduction of CO2 by a masked two-coordinate cobalt(i) complex and characterization of a proposed oxodicobalt(ii) intermediate

Published:2019 Issue:3 Volume:10 Page:918-929
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Roy Lisa¹²³⁴⁵^ORCID,Al-Afyouni Malik H.⁶⁷⁸⁹,DeRosha Daniel E.⁶¹⁰¹¹⁹,Mondal Bhaskar¹²³^ORCID,DiMucci Ida M.¹²¹³¹⁴¹⁵⁹,Lancaster Kyle M.¹²¹³¹⁴¹⁵⁹^ORCID,Shearer Jason⁶¹⁶¹⁷⁹^ORCID,Bill Eckhard¹²³,Brennessel William W.⁶⁷⁸⁹^ORCID,Neese Frank¹⁸²³,Ye Shengfa¹⁸²³^ORCID,Holland Patrick L.⁶¹⁰¹¹⁹^ORCID

Affiliation:

1. Max Planck Institute for Chemical Energy Conversion

2. Mülheim an der Ruhr

3. Germany

4. CSIR Central Mechanical Engineering Research Institute

5. Durgapur 713209

6. Department of Chemistry

7. University of Rochester

8. Rochester

9. USA

10. Yale University

11. New Haven

12. Department of Chemistry and Chemical Biology

13. Baker Laboratory

14. Cornell University

15. Ithaca

16. Trinity University

17. San Antonio

18. Max Planck Institute for Coal Research

Abstract

The detailed mechanism of CO₂ reduction by a cobalt(i) complex is investigated using computations and kinetics.

Funder

U.S. Department of Energy

National Science Foundation

Max-Planck-Gesellschaft

Department of Science and Technology, Ministry of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C8SC02599A

Reference88 articles.

1. Tuning Reactivity and Mechanism in Oxidation Reactions by Mononuclear Nonheme Iron(IV)-Oxo Complexes

2. Bioinspired Nonheme Iron Catalysts for C–H and C═C Bond Oxidation: Insights into the Nature of the Metal-Based Oxidants

3. Nonheme FeIVO Complexes That Can Oxidize the C−H Bonds of Cyclohexane at Room Temperature

4. Reactivity comparison of high-valent iron(iv)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size

5. Oxygen-Atom Transfer Reactivity of Axially Ligated Mn(V)–Oxo Complexes: Evidence for Enhanced Electrophilic and Nucleophilic Pathways

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