Pd(ii)-Catalyzed alkyne annulation through allylic isomerization: synthesis of spiro-cyclopentadiene pyrazolones
Author:
Affiliation:
1. Applied Organic Chemistry
2. Chemical Sciences & Technology Division
3. CSIR-North East Institute of Science and Technology
4. AcSIR-Ghaziabad-201002
5. India
6. Department of Chemical Sciences
7. Tezpur University
8. Tezpur-784028
Abstract
Alkyne annulation reaction proceeds via C(sp2)–H/C(sp3)–H activation and allylic isomerization is described.
Funder
Science and Engineering Research Board
Department of Science and Technology, Ministry of Science and Technology
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC02155A
Reference26 articles.
1. 3d Transition Metals for C–H Activation
2. A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry
3. Recent Advances in Ruthenium(II)-Catalyzed C−H Bond Activation and Alkyne Annulation Reactions
4. Manganese-Catalyzed C–H Activation
5. Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis
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1. A Pd(ii)-catalyzed denitrative alkyne annulation reaction for the synthesis of cyclopenta[b]chromanes;Organic Chemistry Frontiers;2024
2. Ru(ii)-catalyzed oxidative coupling of sulfoxonium ylides with amines: efficient synthesis of α-ketoamides and indolo[2,1-a]isoquinolines;Organic & Biomolecular Chemistry;2023
3. Transition‐Metal‐Catalyzed Synthesis of Spiro Compounds through Activation and Cleavage of C−H Bonds;Asian Journal of Organic Chemistry;2022-11-22
4. Asymmetric [3+2] spiroannulation of pyrazolone-derived Morita–Baylis–Hillman carbonates with alkynyl ketones: facile access to spiro[cyclopentadiene-pyrazolone] scaffolds;Chemical Communications;2022
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