Inhibition of (dppf)nickel-catalysed Suzuki–Miyaura cross-coupling reactions by α-halo-N-heterocycles-Reference-Cited by-同舟云学术

Inhibition of (dppf)nickel-catalysed Suzuki–Miyaura cross-coupling reactions by α-halo-N-heterocycles

Published:2021 Issue:42 Volume:12 Page:14074-14082
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Cooper Alasdair K.¹,Greaves Megan E.¹²^ORCID,Donohoe William¹,Burton Paul M.³,Ronson Thomas O.²^ORCID,Kennedy Alan R.¹^ORCID,Nelson David J.¹^ORCID

Affiliation:

1. WestCHEM Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow, G1 1XL, Scotland, UK

2. Chemical Development, Pharmaceutical Technology and Development, Operations, AstraZeneca, Macclesfield SK10 2NA, UK

3. Syngenta, Jealott′s Hill International Research Centre, Bracknell, Berkshire, RG426EY, UK

Abstract

Nickel complexes with a dppf ligand can form inactive dinickel(ii) complexes during Suzuki–Miyaura cross-coupling reactions. However, these complexes can react with Grignard reagents in Kumada–Tamao–Corriu cross-coupling reactions.

Funder

Syngenta International

AstraZeneca

Engineering and Physical Sciences Research Council

Carnegie Trust for the Universities of Scotland

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC04582B

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