The influence of the FeCp(CO)2+moiety on the dynamics of the metalloid [Ge9(Si(SiMe3)3)3]−cluster in thf: synthesis and characterization by time-resolved absorption spectroscopy
Author:
Affiliation:
1. Institut für Physikalische Chemie
2. Karlsruher Institut für Technologie (KIT)
3. 76131 Karlsruhe
4. Germany
5. Institut für Anorganische Chemie
6. Universität Tübingen
7. 72076 Tübingen
Abstract
Photoexcitation of a newly synthesized, neutral tetrasubstituted Ge9cluster with a covalently bound transition metal substituent led to a complete ground state recovery within 150 ps indicating the strong influence of the Fe moiety.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT02091H
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