Cu(iii)–bis-thiolato complex forms an unusual mono-thiolato Cu(iii)–peroxido adduct-Reference-Cited by-同舟云学术

Cu(iii)–bis-thiolato complex forms an unusual mono-thiolato Cu(iii)–peroxido adduct

Published:2021 Issue:1 Volume:57 Page:69-72
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Donnelly Jane M.¹²³⁴^ORCID,Lermyte Frederik⁵⁶⁷⁸^ORCID,Wolny Juliusz A.⁹¹⁰¹¹⁸^ORCID,Walker Marc⁹²³⁴^ORCID,Breeze Ben G.⁹²³⁴^ORCID,Needham Russell J.⁵²³⁴^ORCID,Müller Christina S.⁹¹⁰¹¹⁸^ORCID,O’Connor Peter B.⁵²³⁴^ORCID,Schünemann Volker⁹¹⁰¹¹⁸^ORCID,Collingwood Joanna F.¹²³⁴^ORCID,Sadler Peter J.⁵²³⁴^ORCID

Affiliation:

1. School of Engineering

2. University of Warwick

3. Coventry CV4 7Al

4. UK

5. Department of Chemistry

6. Technical University of Darmstadt

7. 64287 Darmstadt

8. Germany

9. Department of Physics

10. Technische Universität Kaiserslautern

11. 67663 Kaiserslautern

Abstract

The square-planar complex [bis(toluene-3,4-dithiolato)copper(iii)][NEt₃H], characterised by X-ray photoelectron spectroscopy and DFT, fragments in FTICR-MS to form [(toluene-3,4-dithiolato)Cu(iii)(peroxide)]⁻ by reaction with O₂.

Funder

Biotechnology and Biological Sciences Research Council

Engineering and Physical Sciences Research Council

Horizon 2020 Framework Programme

University of Warwick

US-UK Fulbright Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D0CC06921C

Reference32 articles.

1. Copper Active Sites in Biology

2. High-valent copper in biomimetic and biological oxidations

3. Chemical Plausibility of Cu(III) with Biological Ligation in pMMO

4. Dioxygen Activation at a Single Copper Site: Structure, Bonding, and Mechanism of Formation of 1:1 Cu−O2 Adducts

5. Brain tyrosinase overexpression implicates age-dependent neuromelanin production in Parkinson’s disease pathogenesis

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