Lithium heterocuprates: the influence of the amido group on organoamidocuprate structures
Author:
Affiliation:
1. Department of Chemistry
2. Imperial College London
3. London, UK
Abstract
The structural isomers of a number of lithium heteroamidocuprates LiCuR(NR′2) have been studied in the solid state and in solution, with the steric and electronic properties of the amido group (NR′2) shown to significantly influence the solid-state structures and the position of the solution equilibrium.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00965G
Reference34 articles.
1. N. Krause , Modern organocopper chemistry , Wiley-VCH , Weinheim , 2002
2. R. J. K. Taylor , Organocopper reagents: a practical approach , Oxford University Press , Oxford , 1994
3. Asymmetric conjugate addition
4. Regio- and Stereoselective Syntheses with Organocopper Reagents
5. Remarkable Effect of Silyl Groups on Asymmetric Induction in a Conjugate Addition Reaction with O-Methylnorephedrine-Based N-Silylamidocuprates
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