A new route for the efficient metalation of unfunctionalized aromatics-Reference-Cited by-同舟云学术

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A new route for the efficient metalation of unfunctionalized aromatics

Published:2019 Issue:11 Volume:10 Page:3385-3400
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Peel Andrew J.¹²³⁴,Tezuka Noriyuki⁵⁶⁷⁸⁹,D'Rozario James M.¹²³⁴,Uchiyama Masanobu⁵⁶⁷⁸⁹^ORCID,Wheatley Andrew E. H.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Cambridge

3. Cambridge

4. UK

5. Cluster of Pioneering Research (CPR)

6. Advanced Elements Chemistry Laboratory

7. RIKEN

8. Saitama 351-0198

9. Japan

Abstract

Efficient metalation of benzene is reported for the first time using reagents based only upon a mixture of a copper amide and a lithium amide.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Asahi Glass Foundation

Engineering and Physical Sciences Research Council

Japan Society for the Promotion of Science

Sumitomo Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C8SC04325F

Reference66 articles.

1. TMP−Zincate as Highly Chemoselective Base for Directed Ortho Metalation

2. An alternative picture of alkali-metal-mediated metallation: cleave and capture chemistry

3. Cleave and capture chemistry illustrated through bimetallic-induced fragmentation of tetrahydrofuran

4. Directed ortho-meta′- and meta-meta′ - dimetalations: A template base approach to deprotonation

Cited by 4 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Alkali Metal Metal(ates) Containing Divalent Earth Abundant Transition Metals;CHIMIA;2022-04-27

2. Recent Development in the Solution Structural Chemistry of Main Group Organometallics;Polar Organometallic Reagents;2022-03-04

3. The Road to Aromatic Functionalization by Mixed‐metal Ate Chemistry;Polar Organometallic Reagents;2022-03-04

4. Lipshutz-type bis(amido)argentates for directed ortho argentation;Chemical Science;2020

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