The multiple bonding in heavier group 14 element alkene analogues is stabilized mainly by dispersion force effects-Reference-Cited by-同舟云学术

The multiple bonding in heavier group 14 element alkene analogues is stabilized mainly by dispersion force effects

Published:2015 Issue:11 Volume:6 Page:6235-6244
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Guo Jing-Dong¹²³⁴,Liptrot David J.⁵⁶⁷⁸,Nagase Shigeru¹²³⁴,Power Philip P.⁵⁶⁷⁸

Affiliation:

1. Fukui Institute for Fundamental Chemistry

2. Kyoto University

3. Sakyo-ku, Kyoto

4. Japan 606-8103

5. Department of Chemistry

6. University of California

7. Davis

8. United States

Abstract

Computations on the heavier group 14 dimetallenes [E{CH(SiMe₃)₂}₂]₂ and [E{N(SiMe₃)₂}₂]₂ (E = Ge, Sn, or Pb) and their respective monomers indicated that empirically observed dimerization is principally driven by attractive dispersion forces.

Funder

National Science Foundation

Ministry of Education, Culture, Sports, Science, and Technology

English-Speaking Union

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC02707A

Reference58 articles.

1. Stabilisation of metals in a low co-ordinative environment using the bis(trimethylsilyl)methyl ligand; coloured Sn II and Pb II alkyls, M[CH(SiMe3)2]2