Synthesis and Investigation of a Soluble Distannene with no <i>Trans</i>‐Bent Angle or Twisting in the Solid‐State-Reference-Cited by-同舟云学术

Synthesis and Investigation of a Soluble Distannene with no Trans‐Bent Angle or Twisting in the Solid‐State

Published:2024-03-04 Issue:23 Volume:30 Page:
ISSN:0947-6539
Container-title:Chemistry – A European Journal
language:en
Short-container-title:Chemistry A European J

Author:

Kimmich Roman¹,Kern Ralf H.¹,Strienz Markus¹,Koldemir Aylin²,Eichele Klaus¹,Pöttgen Rainer²,Wesemann Lars¹,Schnepf Andreas¹^ORCID

Affiliation:

1. Department of Inorganic Chemistry University of Tübingen Auf der Morgenstelle 18 72076 Tübingen Germany

2. Department of Inorganic and Analytical Chemistry University of Münster Corrensstraße 30 D-48149 Münster

Abstract

AbstractBy treating KSiiPr3 with Sn[N(SiMe3)2]2 the distannene Sn2(TIPS)4 (TIPS=SiiPr3) is formed in a metathesis reaction. The crystal structure analysis of Sn2(TIPS)4 reveals a planar arrangement of the substituents in the solid‐state and hence the second planar alkene like distannene of its kind. Due to the TIPS substituents, Sn2(TIPS)4 is well soluble in all commonly used organic solvents, opening the door for various analytics and reactivity studies. Due to its stability in solution, various reactions can be performed such as cycloaddition reactions with 2,3‐dimethyl‐1,3‐butadiene (DMBD) and TMS‐azide.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Wiley

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