The C(3P) + O2(3Σg−) → CO2 ↔ CO(1Σ+) + O(1D)/O(3P) reaction: thermal and vibrational relaxation rates from 15 K to 20 000 K-Reference-Cited by-同舟云学术

The C(3P) + O2(3Σg−) → CO2 ↔ CO(1Σ+) + O(1D)/O(3P) reaction: thermal and vibrational relaxation rates from 15 K to 20 000 K

Published:2021 Issue:19 Volume:23 Page:11251-11263
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

San Vicente Veliz Juan Carlos¹²³⁴^ORCID,Koner Debasish¹²³⁴^ORCID,Schwilk Max¹²³⁴⁵^ORCID,Bemish Raymond J.⁶⁷⁸⁹^ORCID,Meuwly Markus¹²³⁴¹⁰^ORCID

Affiliation:

1. Department of Chemistry

2. University of Basel

3. CH-4056 Basel

4. Switzerland

5. University of Vienna

6. Air Force Research Laboratory

7. Space Vehicles Directorate

8. Kirtland AFB

9. USA

10. Brown University

Abstract

Reaction and vibrational relaxation rate computed for C(³P) + O₂(³Σ_g⁻) ↔ CO(¹Σ⁺) + O(¹D)/O(³P) for a wide range of temperatures using quasiclassical trajectory calculations on five new potential energy surfaces for different electronic states.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Air Force Office of Scientific Research

Universität Basel

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP01101D

Reference72 articles.

1. Experimental and Numerical Investigation of Hypervelocity Carbon Dioxide Flow over Blunt Bodies