Electronic effect of a perfluorinated β-diketiminate ligand on the bonding nature of copper carbonyl complexes-Reference-Cited by-同舟云学术

Electronic effect of a perfluorinated β-diketiminate ligand on the bonding nature of copper carbonyl complexes

Published:2020 Issue:28 Volume:49 Page:9773-9780
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Huse Kevin¹²³⁴,Weinert Hanns¹²³⁴^ORCID,Wölper Christoph¹²³⁴,Schulz Stephan¹²³⁴^ORCID

Affiliation:

1. Faculty of Chemistry and Center for NanoIntegration Duisburg-Essen (CENIDE)

2. University of Duisburg-Essen

3. D-45117 Essen

4. Germany

Abstract

A combined experimental and computational study demonstrates the influence of fluorine substituents on the electronic properties of β-diketiminate ligands.

Funder

Universität Duisburg-Essen

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT01943G

Reference30 articles.

1. The chemistry of univalent metal β-diketiminates

2. Tuning steric and electronic effects in transition-metal β-diketiminate complexes

3. The unique β-diketiminate ligand in aluminum(i) and gallium(i) chemistry

4. β-Diketiminate complexes of the first row transition metals: applications in catalysis

5. Fluorination of Cyclometalated Iridium β-Ketoiminate and β-Diketiminate Complexes: Extreme Redox Tuning and Ligand-Centered Excited States

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