Alkyl backbone variations in common β-diketiminate ligands and applications to <i>N</i>-heterocyclic silylene chemistry-Reference-Cited by-同舟云学术

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Alkyl backbone variations in common β-diketiminate ligands and applications to N-heterocyclic silylene chemistry

Published:2024 Issue:23 Volume:53 Page:9887-9895
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bourne Connor¹,Dong Huanhuan¹,McKain Katharine¹,Mayer Lena C.¹,McKay Aidan P.¹,Cordes David B.¹^ORCID,Slawin Alexandra M. Z.¹^ORCID,Stasch Andreas¹^ORCID

Affiliation:

1. EaStCHEM School of Chemistry, University of St Andrews, North Haugh, St Andrews, KY16 9ST, UK

Abstract

Syntheses of β-diketimines, alkali–metal complexes, and N-heterocyclic silylene derivatives are presented and the impact of ligand backbone modifications are discussed.

Funder

Engineering and Physical Sciences Research Council

China Scholarship Council

University of St Andrews

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01298D

Reference69 articles.

1. The Chemistry of β-Diketiminatometal Complexes

2. The chemistry of univalent metal β-diketiminates

3. β-Diketiminate and β-Ketoiminate Metal Catalysts for Ring-Opening Polymerization of Cyclic Esters

4. S.Ito and Y.Morimoto , β-Diketiminates as Redox Non-innocent Supporting Ligands in Coordination Chemistry , in Chemical Science of π-Electron Systems , ed. T. Akasaka , et al. , Springer , Japan 2016

5. On the non-innocence of “Nacnacs”: ligand-based reactivity in β-diketiminate supported coordination compounds

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