Thermodynamics and high-pressure kinetics of a fast carbon dioxide fixation reaction by a (2,6-pyridinedicarboxamidato-hydroxo)nickel(ii) complex-Reference-Cited by-同舟云学术

Thermodynamics and high-pressure kinetics of a fast carbon dioxide fixation reaction by a (2,6-pyridinedicarboxamidato-hydroxo)nickel(ii) complex

Published:2014 Issue:14 Volume:43 Page:5274-5279
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Troeppner O.¹²³,Huang D.⁴⁵⁶,Holm R. H.⁴⁵⁶,Ivanović-Burmazović I.¹²³

Affiliation:

1. Department of Chemistry and Pharmacy

2. University of Erlangen-Nürnberg

3. Erlangen, Germany

4. Department of Chemistry and Chemical Biology

5. Harvard University

6. Cambridge, USA

Abstract

The thermodynamics and high-pressure kinetics of the fastest CO₂ fixation reaction by a metal-bound hydroxide resulted in a clear mechanistic picture and characterization of a very compact five-coordinate transition state.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C3DT53004C

Reference65 articles.

1. Electrocatalytic CO 2 Conversion to Oxalate by a Copper Complex

2. Transformation of Carbon Dioxide

3. Kinetics and mechanistic analysis of an extremely rapid carbon dioxide fixation reaction

4. Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation

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