Rapid atmospheric carbon dioxide fixation by nickel(ii) complexes: meridionally coordinated diazepane-based 3N ligands facilitate fixation

Author:

Ajaykamal Tamilarasan1234ORCID,Sharma Mitu5674ORCID,Islam Nasreen S.5674ORCID,Palaniandavar Mallayan1234ORCID

Affiliation:

1. School of Chemistry

2. Bharathidasan University

3. Tiruchirappalli 620024

4. India

5. Department of Chemical Sciences

6. Tezpur University

7. Tezpur

Abstract

In basic methanol solution, [Ni(3N)(H2O)3]2+1, where 3N is a meridionally coordinated ligand, absorbs atmospheric CO2 rapidly to produce 3, [Ni2(3N)2(μ-CO3)(H2O)2](ClO4)2. 3 catalyses the conversion of styrene epoxide into cyclic carbonate.

Funder

Indian National Science Academy

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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