Rapid atmospheric carbon dioxide fixation by nickel(ii) complexes: meridionally coordinated diazepane-based 3N ligands facilitate fixation
Author:
Affiliation:
1. School of Chemistry
2. Bharathidasan University
3. Tiruchirappalli 620024
4. India
5. Department of Chemical Sciences
6. Tezpur University
7. Tezpur
Abstract
In basic methanol solution, [Ni(3N)(H2O)3]2+1, where 3N is a meridionally coordinated ligand, absorbs atmospheric CO2 rapidly to produce 3, [Ni2(3N)2(μ-CO3)(H2O)2](ClO4)2. 3 catalyses the conversion of styrene epoxide into cyclic carbonate.
Funder
Indian National Science Academy
Science and Engineering Research Board
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00299F
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