Occurrence of a µ-SiF interaction in bimetallic trifluorosilyl complexes
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1992/DT/DT9920000903
Reference38 articles.
1. Komplexe mit einer η2-μ2-SiO-Brücke; Struktur des Zweikernkomplexes [Fe(CO)3-{μ-Si(OMe)2OMe}(μ-dppm)PdCl](Fe–Pd)
2. Complexes with an ?2-?2-SiO Bridge. Structure of the Bimetallic Complex
3. Synthesis and structure of bimetallic allyl, alkoxysilyl complexes [Fe{Si(OMe)3}(CO)3(.mu.-dppm)M(.eta.3-2-RC3H4)] M = Pd, Pt; R = H, Me) and of [Fe{.mu.-Si(OMe)2(OMe)}(CO)3(.mu.-dppm)Pd(SnPh3)], a Sn-Pd-Fe-Si chain complex with a .mu.2-.eta.2-SiO bridge
4. Synthesis and reactivity of phosphine-substituted hydrido silyl complexes mer-[FeH(SiR3)(CO)3{Ph2P(CH2)nPPh2}](n= 1 or 4), mer-[FeH{Si(OMe)3}(CO)3(PPh2H)] and mer-[FeH{Si(OMe)3}(CO)3{Ph2PCH2C(O)Ph}]. Synthesis of bimetallic complexes and crystal structure of mer-[(Ph3P)Cu(µ-dppm)Fe{Si(OMe)3}(CO)3]
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