Synthesis and reactivity of phosphine-substituted hydrido silyl complexes mer-[FeH(SiR3)(CO)3{Ph2P(CH2)nPPh2}](n= 1 or 4), mer-[FeH{Si(OMe)3}(CO)3(PPh2H)] and mer-[FeH{Si(OMe)3}(CO)3{Ph2PCH2C(O)Ph}]. Synthesis of bimetallic complexes and crystal structure of mer-[(Ph3P)Cu(µ-dppm)Fe{Si(OMe)3}(CO)3]
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1991/DT/DT9910001507
Reference34 articles.
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4. Hydrido(triphenylsilyl)tetracarbonyliron derivatives with phosphine ligands
5. Reactivity of Fe(CO)4(H)MPh3 (M = Si, Ge) and mechanism of substitution by two-electron-donor ligands: implications for the mechanism of hydrosilylation of olefins catalyzed by iron pentacarbonyl
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