Bonding and uneven charge distribution in infinite pyrene π-stacks

Author:

Flynn Chase1,Zhou Zheng23ORCID,McCormack Megan E.2,Wei Zheng2ORCID,Petrukhina Marina A.2ORCID,Kertesz Miklos1ORCID

Affiliation:

1. Chemistry Department and Institute of Soft Matter, Georgetown University, 37th and O Streets, NW, Washington DC 20057-1227, USA

2. Department of Chemistry, University at Albany, State University of New York, 1400 Washington Avenue, Albany, NY 12222, USA

3. School of Materials Science and Engineering, Tongji University, 4800 Cao'an Road, Shanghai 201804, China

Abstract

Unusual intermolecular π-stacking in a new charge transfer salt of pyrene (Py), (Py)2+(Ga2Cl7), has been observed.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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