A unique trimeric triphenylene radical cation: stacking aggregation, bonding, and stability-Reference-Cited by-同舟云学术

A unique trimeric triphenylene radical cation: stacking aggregation, bonding, and stability

Published:2024 Issue: Volume: Page:
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Bhattacharjee Rameswar¹^ORCID,McCormack Megan E.²,Zhou Zheng²³^ORCID,Wei Zheng²^ORCID,Petrukhina Marina A.²^ORCID,Kertesz Miklos¹^ORCID

Affiliation:

1. Department of Chemistry and Institute of Soft Matter, Georgetown University, 37th and O Streets, NW, Washington, DC 20057-1227, USA

2. Department of Chemistry, University at Albany, State University of New York, 1400 Washington Avenue, Albany, NY 12222, USA

3. School of Materials Science and Engineering, Tongji University, 4800 Cao'an Road, Shanghai 201804, China

Abstract

A unique trimeric radical cation with unequal charge distribution is obtained by chemical oxidation of triphenylene with GaCl3. XRD determined structure is combined with computational modeling showing stabilizing pancake bonding in the π-stacks.

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC03774J

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