The direct determination of partial molar volumes and reaction volumes in ultra-dilute non-reactive and reactive multi-component systems using a combined spectroscopic and modified response surface model approach
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2006/DT/B515298D
Reference34 articles.
1. Semi-Batch Homogeneous Catalytic In-Situ Spectroscopic Data. FTIR Spectral Reconstructions Using Band-Target Entropy Minimization (BTEM) without Spectral Preconditioning
2. The Rh4(CO)12-Catalyzed Hydroformylation of 3,3-Dimethylbut-1-ene Promoted with HMn(CO)5. Bimetallic Catalytic Binuclear Elimination as an Origin for Synergism in Homogeneous Catalysis
3. Spectral reconstruction of in situ FTIR spectroscopic reaction data using band-target entropy minimization (BTEM): application to the homogeneous rhodium catalyzed hydroformylation of 3,3-dimethylbut-1-ene using Rh4(CO)12
4. The development of a response surface model for the determination of infinite dilution partial molar volumes and excess volumes from dilute multi-component data alone. Implications for the characterization of non-isolatable solutes in complex homogeneous reactive systems
5. Tetranuclear and dinuclear phosphine- and arsine-substituted rhodium carbonyls; infrared spectral evidence for the formation of dirhodium octacarbonyl
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2. Combining in situ FTIR spectroscopy, BTEM analysis, bulk density measurements and DFT for two Diels–Alder reactions. A general approach for partial molar volume and reaction volume analyses;RSC Advances;2014
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