Semi-Batch Homogeneous Catalytic In-Situ Spectroscopic Data. FTIR Spectral Reconstructions Using Band-Target Entropy Minimization (BTEM) without Spectral Preconditioning
Author:
Affiliation:
1. Department of Chemical and Environmental Engineering, 4 Engineering Drive 4, National University of Singapore, Singapore 119260
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om010933j
Reference23 articles.
1. Band-Target Entropy Minimization (BTEM): An Advanced Method for Recovering Unknown Pure Component Spectra. Application to the FTIR Spectra of Unstable Organometallic Mixtures
2. Infrared spectroscopic studies on metal carbonyl compounds. 24. Observation of the infrared spectrum of an acylrhodium tetracarbonyl during the hydroformylation of olefins with rhodium-containing catalyst precursors
3. Kinetics of the formation and hydrogenolysis of acylrhodium tetracarbonyl
4. Liquid-Phase Reaction of Monosubstituted and Disubstituted Alkynes with Tetrarhodium Dodecacarbonyl under CO and CO/H2 Mixtures. In-Situ IR Spectroscopic Characterization of 20 New Alkyne−Rhodium Complexes
5. α= 1.0,α= 1.0,α= 3.0,α= 1.0,α= 1.0, andα= 5.0 are used in eq 8 or eq 16 for the targeted regions 1733−1735, 1640−1644, 1885−1887, 2020−2023, 2067.5−2068.5, and 1818−1820 cm-1, respectively.
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