Mechanistic insight into the thermal activation of Togni's trifluoromethylation reagents
Author:
Affiliation:
1. Department of Chemistry and Applied Biosciences
2. Swiss Federal Institute of Technology (ETH) – Zürich
3. CH-8093 Zürich
4. Switzerland
Abstract
The thermal activation of Togni's reagent was studied by GC-MS and shown to generate CF3 and, concomitantly, alkyl radicals.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP01396E
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1. The Trifluoromethyl Group in Medical Chemistry
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