Challenges in cyclometalation: steric effects leading to competing pathways and η1,η2-cyclometalated iridium(iii) complexes-Reference-Cited by-同舟云学术

Challenges in cyclometalation: steric effects leading to competing pathways and η1,η2-cyclometalated iridium(iii) complexes

Published:2018 Issue:37 Volume:47 Page:13046-13051
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Chen Houguang Jeremy¹²³⁴⁵^ORCID,Teo Ronald Hong Xiang¹²³⁴⁵^ORCID,Wong Jonathan¹²³⁴⁵,Li Yongxin¹²³⁴⁵,Pullarkat Sumod A.¹²³⁴⁵^ORCID,Leung Pak-Hing¹²³⁴⁵^ORCID

Affiliation:

1. Division of Chemistry and Biological Chemistry

2. School of Physical and Mathematical Sciences

3. Nanyang Technological University

4. Singapore 637371

5. Singapore

Abstract

The iridation of a known cyclometalating ligand led to several products, one of which is an olefin-directed carbocyclic iridacycle. The mechanistic pathways to the formation of these compounds were investigated.

Funder

Ministry of Education - Singapore

Nanyang Technological University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT02639D

Reference52 articles.

1. Iridacycles for hydrogenation and dehydrogenation reactions

2. Our Odyssey with Functionalized Chiral Phosphines: From Optical Resolution to Asymmetric Synthesis to Catalysis