Pd/C-catalyzed synthesis of oxamates by oxidative cross double carbonylation of alcohols and tertiary amines through C

Pd/C-catalyzed synthesis of oxamates by oxidative cross double carbonylation of alcohols and tertiary amines through C–N bond cleavage

Published:2019 Issue:46 Volume:43 Page:18072-18078
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Kolekar Yuvraj A.¹²³⁴,Bhanage Bhalchandra M.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Institute of Chemical Technology

3. Mumbai-400019

4. India

Abstract

Palladium-catalyzed oxidative cross double carbonylation reaction between tertiary amines and alcohols using oxidant O₂ and KI as the additive affords oxamates. Oxamate are as a intermediate in biological active compound and glycol synthesis.

Funder

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C9NJ04156G

Reference47 articles.

1. Practical formal total synthesis of (rac)- and (S)-camptothecin

2. Increased Yields and Simplified Purification with a Second-Generation Cobalt Catalyst for the Oxidative Formation of trans-THF Rings

3. Novel steroid mimics: synthesis of tri- and tetra-substituted oxamides and oxoamides

4. Practical Synthesis of Functionalized 1,5-Disubstituted 1,2,4-Triazole Derivatives

5. Visible‐Light‐Driven, One‐pot Amide Synthesis Catalyzed by the B 12 Model Complex under Aerobic Conditions

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