Rh(<scp>iii</scp>)-catalyzed [4+1] annulation of a sulfoxonium ylide with allyl alkyl ethers: a detailed theoretical study of the anti-inflammatory and antidiabetic activities with DFT-Reference-Cited by-同舟云学术

Rh(iii)-catalyzed [4+1] annulation of a sulfoxonium ylide with allyl alkyl ethers: a detailed theoretical study of the anti-inflammatory and antidiabetic activities with DFT

Published:2024 Issue: Volume: Page:
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Sivakumar Pakkirisamy¹²,Ganesh Pothapragada S. K. Prabhakar³,Muthuraja Perumal⁴⁵,Bharanidharan Sarangapani⁶,Anandhan Balasubramaniyan¹,Rajamohan Rajaram⁵⁷^ORCID,Kamatchi Subramaniyan²

Affiliation:

1. Department of Chemistry, Saraswathy College of Engineering and Technology, Olakkur, Tindivanam, 604 305, Tamil Nadu, India

2. PG & Research Department of Chemistry, Government Arts College, Chidambaram, 608 102, Tamil Nadu, India

3. Department of Chemistry, Indian Institute of Science Education and Research (IISER) Tirupati, Tirupati, 517 507, Andhra Pradesh, India

4. Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati, 781 039, Assam, India

5. Organic Materials Synthesis Laboratory, School of Chemical Engineering, Yeungnam University, Gyeongsan 38541, Republic of Korea

6. Department of Physics, Panimalar Engineering College, Chennai, 600 123, Tamil Nadu, India

7. Department of Physiology, Saveetha Dental College and Hospitals, Saveetha Institute of Medical and Technical Science (SIMATS), Saveetha University, Chennai 600 077, India

Abstract

The [4+1] annulation of sulfoxonium ylides with allyl ether, catalyzed by Rh(iii), efficiently produces alkyl-substituted indanone with a broad substrate scope and excellent yield.

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NJ/D4NJ03140G

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