Pyrazine-imide complexes: reversible redox and MOF building blocks-Reference-Cited by-同舟云学术

Pyrazine-imide complexes: reversible redox and MOF building blocks

Published:2015 Issue:6 Volume:44 Page:2880-2892
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Cowan Matthew G.¹²³⁴,Miller Reece G.¹²³⁴,Brooker Sally¹²³⁴

Affiliation:

1. Department of Chemistry and the MacDiarmid Institute for Advanced Materials and Nanotechnology

2. University of Otago

3. Dunedin 9054

4. New Zealand

Abstract

Stepwise exchange of pyrazine for pyridine, in three bis-heterocycle-based imide ligands, tunes the potential of the [M^II/III(ligand)₂]^0/+ redox couple, increasing the stability of the M^II oxidation state by about 0.1 V per exchange.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03407D

Reference36 articles.

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3. Hydrolysis reactions of 2,4,6-tris(2-pyrimidyl)- and 2,4,6-tris(2-pyridyl)-1,3,5-triazines with divalent copper. Structure of a bis(2-pyrimidylcarbonyl)aminocopper(II) complex

4. A Binuclear Fe(III)Dy(III) Single Molecule Magnet. Quantum Effects and Models

5. Effects of 3d–4f Magnetic Exchange Interactions on the Dynamics of the Magnetization of DyIII-MII-DyIII Trinuclear Clusters

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