Unexpected lability of the [RuIII(phtpy)Cl3] complex-Reference-Cited by-同舟云学术

Unexpected lability of the [RuIII(phtpy)Cl3] complex

Published:2017 Issue:44 Volume:46 Page:15567-15572
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Benavides Paola A.¹²³⁴⁵^ORCID,Matias Tiago A.¹²³⁴⁵^ORCID,Araki Koiti¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Institute of Chemistry

3. University of São Paulo

4. São Paulo

5. Brazil

Abstract

[Ruⁱⁱⁱ(phtpy)Cl₃] complex is labile and releases terdentate phtpy ligand in solution leading to the formation of the homoleptic [Ruⁱⁱ(phtpy)₂] complex as main product instead of the desired [Ru(phtpy)(LL)Cl] complex upon reaction with bidentated LL ligands.

Funder

Fundação de Amparo à Pesquisa do Estado de São Paulo

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT03658B

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