The siliconyl, boronyl, and iminoboryl ligands as analogues of the well-known carbonyl ligand: predicted reactivity towards dipolar cyclooligomerization in iron/cobalt carbonyl complexes-Reference-Cited by-同舟云学术

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The siliconyl, boronyl, and iminoboryl ligands as analogues of the well-known carbonyl ligand: predicted reactivity towards dipolar cyclooligomerization in iron/cobalt carbonyl complexes

Published:2015 Issue:45 Volume:5 Page:35558-35563
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Zhang Zhong¹²³⁴⁵,Pu Liang¹²³⁴,Li Qianshu⁵⁶⁷⁴,King R. Bruce⁸⁹¹⁰¹¹

Affiliation:

1. College of Science

2. Northwest A&F University

3. Yangling

4. P. R. China

5. Center for Computational Quantum Chemistry

6. South China Normal University

7. Guangzhou 510631

8. Department of Chemistry and Center for Computational Chemistry

9. University of Georgia

10. Athens

11. USA

Abstract

The Fe(CO)₄(SiO), Co(CO)₄(BO), and Co(CO)₄(BNSiMe₃), complexes akin to the well-known Fe(CO)₅ are predicted by density functional theory to undergo exothermic oligomerization to give the oligomers containing Si_nO_n/B_nO_n/B₂N₂ rings with single bonds.

Funder

Division of Chemistry

China Postdoctoral Science Foundation

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA01903F

Reference63 articles.

1. A. G. Sharpe , Chemistry of Cyano Complexes of the Transition Metals, Academic, London, 1976

2. Emergence of a CNH and cyano complex based organometallic chemistry

3. G. B. Richter-Addo and P.Legzdins, Metal Nitrosyls, Oxford University Press, New York, 1992

4. Coordination and Organometallic Chemistry of Metal−NO Complexes

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