P2S2-Bridged binuclear metal carbonyls from dimerization of coordinated thiophosphoryl groups: a theoretical study-Reference-Cited by-同舟云学术

P2S2-Bridged binuclear metal carbonyls from dimerization of coordinated thiophosphoryl groups: a theoretical study

Published:2020 Issue:30 Volume:44 Page:12942-12948
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Zhang Zhong¹²³⁴^ORCID,Chen Zuqing¹²³⁴,Yang Zhipeng¹²³⁴,Wang Jianping¹²³⁴,Pu Liang¹²³⁴^ORCID,Zhao Lingzhi⁵⁶⁷,King R. Bruce⁸⁹¹⁰¹¹^ORCID

Affiliation:

1. College of Chemistry & Pharmacy

2. Northwest A&F University

3. Yangling

4. P. R. China

5. SCNU Qingyuan Institute of Science and Technology Innovation Co., Ltd

6. Qingyuan 511517

7. China

8. Department of Chemistry and Center for Computational Chemistry

9. University of Georgia

10. Athens

11. USA

Abstract

Theoretical studies indicate the complexes M(CO)_n(PS) with bent 1-e/2-e donor PS groups to be unstable for giving the stable M(CO)_n−1(PS) with linear 3-e donor PS groups. In addition, only Mn₂(CO)₈(P₂S₂) is energetically viable from the Mn(CO)₄(PS).

Funder

National Natural Science Foundation of China

Science and Technology Planning Project of Guangdong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/NJ/D0NJ02299C

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