The formation of p-toluic acid from coumalic acid: a reaction network analysis
Author:
Affiliation:
1. Department of Chemical and Biological Engineering
2. Iowa State University
3. Ames
4. USA
5. NSF Engineering Research Center for Biorenewable Chemicals (CBiRC)
Abstract
Diels–Alder cycloaddition of biomass-derived 2-pyrone coumalic acid (CMA) with propylene provides an alternative pathway to produce toluic acid (TA), a precursor to terephthalic acid (TPA) which is a key component in the manufacture of polyethylene terephthalate (PET).
Funder
National Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Pollution,Environmental Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/GC/C7GC01290J
Reference20 articles.
1. Upgrading malic acid to bio-based benzoates via a Diels–Alder-initiated sequence with the methyl coumalate platform
2. Replacing fossil based PET with biobased PEF; process analysis, energy and GHG balance
3. Aromatics from pyrones: esters of terephthalic acid and isophthalic acid from methyl coumalate
4. Green and sustainable manufacture of chemicals from biomass: state of the art
5. Degradation of terephthalic acid in a photocatalytic system able to work also at high pressure
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