Upgrading malic acid to bio-based benzoates via a Diels–Alder-initiated sequence with the methyl coumalate platform

Author:

Lee Jennifer J.123,Pollock III Gerald R.123,Mitchell Donald123,Kasuga Lindsay123,Kraus George A.123

Affiliation:

1. Department of Chemistry and NSF Engineering Research Center for Biorenewable Chemicals

2. Iowa State University

3. Ames, USA

Abstract

Malic acid dimerization was optimized to methyl coumalate from which a Diels–Alder strategy produced a variety of bio-based benzoates.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference51 articles.

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4. K. Kersch , Market Report for Center for Biorenewable Chemicals, Boston, MA, May 2013

5. B. Lepoittevin and P.Roger, in Handbook of Engineering and Specialty Thermoplastics, ed. S. Thomas and P. M. Visakh, Wiley-Scrivener, Hoboken, 2011, vol. 3, pp. 97–126

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