Synthesis of triarylmethanes by silyl radical-mediated cross-coupling of aryl fluorides and arylmethanes-Reference-Cited by-同舟云学术

Synthesis of triarylmethanes by silyl radical-mediated cross-coupling of aryl fluorides and arylmethanes

Published:2023 Issue:16 Volume:14 Page:4248-4256
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zhou Jun¹^ORCID,Zhao Zhengyu¹,Jiang Bingyao²,Yamamoto Katsuhiro²^ORCID,Sumii Yuji²,Shibata Norio¹²^ORCID

Affiliation:

1. Department of Nanopharmaceutical Sciences, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555, Japan

2. Department of Life Science and Applied Chemistry, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555, Japan

Abstract

Silylboronate-mediated radical cross-coupling of aryl fluorides with arylalkanes is disclosed for the efficient defluoroalkylation enabling a mild construction of a new C–C bond by selectively coupling a C(sp2)–F and C(sp3)–H bond.

Funder

Core Research for Evolutional Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC00154G

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